主として分子集合体を例にとり,過去40年間にわたって筆者の身の回りで見聞したユニークな装置の発展や特長的な実験結果を述べてきた。鉱物,金属,無機化合物,合成高分子,医薬品,生体物質,その他の分野でも大きな進展があるが,本記述が学会全体の発展過程を映し出す鏡となることを期待したものである。非平衡凍結系や不可逆過程,生体系への実験的研究や更なる熱量計のミクロ化への大きな期待についても触れた。
Developments of microcalorimeters for combustion, heat capacity, and solution calorimetry that have been done in our Society over the past four decades are surveyed. Unique experimental results obtained for several equilibrium and nonequilibrium systems are reviewed in some details. Molecular systems are the main of these topics, hoping that the description reflects the development of other fields in our Society, including metals, inorganic and organic substances, synthetic polymers, and biological materials. Some remarks for further works based on personal experiences are given in this article.
Publication Date: 2004-11-30